As a 5000m runner, Domínguez won a bronze at the 1998 European Athletics Championships and reached the global podium at the 2001 World Championships in Athletics, winning the silver medal. She scored a gold medal double in 2002 by taking a 3000 metres win at the European Athletics Indoor Championships, before going on to become European champion at the 2002 European Championships. She achieved silver medals in the same events at the IAAF World Indoor Championships and 2003 World Championships in Athletics the following year. She retained her European crown at the 2006 European Athletics Championships.
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